Correction: Nitro-redox reactions at a frustrated borane/phosphane Lewis pair
نویسندگان
چکیده
منابع مشابه
Frustrated Lewis pair chemistry.
Frustrated Lewis pair (FLP) chemistry, a concept that has emerged in the last decade, presents unique systems capable of metal-free hydrogenation by using simple combinations of cooperative main group element components. This finding is particularly interesting given that hydrogenation is a chemical reaction that is performed on a huge scale worldwide with current technologies relying on metal-...
متن کاملFrustrated Lewis Pair Chemistry: Searching for New Reactions.
Frustrated Lewis pair chemistry has taken a steep development in the recent years. It offers possibilities of developing new variants of known reactions and of finding new chemical transformations. This is demonstrated and described by the recently developed FLP-formylborane chemistry, which has led to the formation of the unique (η2 -formylborane)FLP adducts and opened a way of preparing a gen...
متن کاملEthene/alkyne exchange reaction at an intramolecular frustrated Lewis pair.
A vicinal ethylene bridged S/B frustrated Lewis pair (FLP) in situ generated by a hydroboration reaction of phenyl vinyl sulfide, reacts with p-tert-butylphenylacetylene by ethene/alkyne exchange and subsequent 1,2-addition of a second alkyne equivalent to give a zwitterionic sulfonium/borate product.
متن کاملCyclopropane formation under frustrated Lewis pair conditions.
Reaction of the -CH2OSiMe3 substituted allyldimesitylphosphane 5 with HB(C6F5)2 resulted in a hydroboration/(C6F5)2BOSiMe3 elimination sequence to give the phosphinomethyl substituted cyclopropane derivative , probably via a phosphiranium type intermediate. Addition of B(C6F5)3 to compound gave the stable phosphiranium/borate zwitterion that was isolated and characterized by X-ray diffraction.
متن کاملFrustrated Lewis pair behavior of a neutral scandium complex.
An easily-accessible neutral scandium complex Sc[OC(CH3)2CH2PPh2][O-2,6-tBu2-C6H3]2[THF] behaves as a reactive Sc/P frustrated Lewis pair, which when added to organic and inorganic substrates e.g. carbonyl compounds, transition-metal chlorides, and diazoalkane compounds, yields unique and intriguing addition products such as a Sc/Rh heterobimetallic complex and a Sc phosphazine complex.
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2017
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c7dt90093g